I think the most mathematically natural way to interpret negative indices is to threat them as numbers modulo list length. Then 0 = length, and -1 = length - 1.
Negative indices have an implied ”len(list)” in front of them. They can be seen as an application of the idea of half-open intervals (0 <= i < len(list)), so it makes sense that they’re not symmetrical.
I'm not sure on what principles you'd make a principled justification. My most common use of negative indices is for slicing the end of the list, in which context the interpretation similar to len(list) makes sense. E.g., list[:-2] does what you'd expect (the same as list[2:], except from the other end).
> implicitly taking indices mod len(list)?
Isn't this doing that (plus some bounds checking)? -1 mod 4 evaluates to 3.