Which is correct? Remove the non-self part.
"He took care of I." "He took care of me."
"Me" is correct because it's the object.
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"My brother and I climbed a hill." "My brother and me climbed a hill."
"I climbed a hill." "Me climbed a hill."
"I" is correct because it's the subject.
This is a real grammatical rule. It is prescriptive, that's what grammar means.
You can keep not believing it, but that does not make it any less true.